Effects of Different Nanocarbon Materials on the Properties of Al/MoO3/NCM Thermite Prepared by Electrostatic Spinning.

Abstract

In order to improve thermal conductivity, energy performance, and combustion performance of the aluminum-containing thermite, nanocarbon materials were added to thermite. Aluminum/molybdenum and trioxide/nanocarbon materials (Al/MoO3/NCM) were fabricated by electrostatic spinning technology. The Al and MoO3 particles of the nAl/MoO3/NCM thermite are much smaller than nitrocellulose (NC); thus, the two components can be better attached to NC fibers. Results on thermal conductivity demonstrated that the addition of NCM can improve the thermal conductivity of Al/MoO3, and the addition of reduced graphene oxide (RGO) has a more significant impact on thermal conductivity. Energy performance analysis results indicated that the energy performance of Al/MoO3/NCM thermite spinning is the best when the value of combustion oxygen equivalent ratio (Φ) is 0.90–1.00. The combustion performance results show that the addition of NCM can significantly increase the combustion rate of thermites, and the addition of RGO improves its combustion rate the most, followed by carbon nanotubes (CNT) and nanoflake graphite (NFG) being the lowest. By changing the shape of the Al/MoO3/NCM charge and the internal composition of the charge, the sensitivity of the agent can be adjusted, and the matching performance and use performance of the electric igniter can be improved.