Abstract

This work documents the annealing effect on the thermal conductivity of nanotube film (CNTB) and carbon nanotube fiber (CNTF). The thermal properties of carbon nanotube samples are measured by using the transient electro-thermal (TET) technique, and the experimental phenomena are analyzed based on numerical simulation. During the current annealing treatment, CNTB1 always maintains the negative temperature coefficient of resistance (TCR), and its thermal diffusivity increases gradually. When the annealing current is 200 mA, it increases by 33.62%. However, with the increase of annealing current, the TCR of CNTB2 changes from positive to negative. The disparity between CNTB2 and CNTB1 suggests that they have different physical properties and even structures along their lengths. The high-level thermal diffusivity of CNTB2 and CNTF are 2.28–2.46 times and 1.65–3.85 times higher than the lower one. The results show that the decrease of the thermal diffusivity for CNTB2 and CNTF is mainly caused by enhanced Umklapp scattering, the high thermal resistance and torsional sliding during high temperature heating.

Highlights

  • Carbon nanotubes (CNTs) have progressively attracted researchers’ attention for their lightweight, small size and acceptable flexibility

  • The decreasing voltage along with time demonstrate that the MWCNTs dominate the heat conduction in CNTB1 because most carbon materials have a negative temperature coefficient of resistance (TCR) [15]

  • The disparate phenomenon of CNTB2 and CNTB1 indicates that they have different physical properties and even structures along their length directions, which lead to the occurrence of different heat conduction mechanisms

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Summary

Introduction

Carbon nanotubes (CNTs) have progressively attracted researchers’ attention for their lightweight, small size and acceptable flexibility They have both excellent electrical and thermal conductivity, which determines that they have application value and development potential as a high-performance reinforcement material [1]. Studies have shown that high temperature annealing is an effective approach to improve the structure and thermal conductivity of carbon materials [8,9]. The effect of high temperature annealing on the thermal conductivity of carbon materials is complicated, for which a mechanism has yet to be figured out. Nanomaterials 2022, 12, 83 can be accomplished in a few seconds for the sample annealing treatment. Data is collected byInusing the TET technique, and variation of thermal with this work, the focus is on thethe current annealing effect diffusivity on CNTB and CNTF. The evolution of material microstructures is studied base on the variation of their thermal properties

Materials
Figure
Transient
Experimental Procedure
Positive Effect of Annealing on CNTB1
Observation of Thermal Diffusivity Jump on CNTB2 and CNTF
Partial
Temperature Distribution and Thermal Conductivity Change of CNTB
Temperature Distribution and Thermal Conductivity Change of CNTF
Mechanism
Effects on Thermal Conductivity
Effects of Annealing on Structure
Conclusions
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