Abstract

The crystal structure of Na[Co(NC 6H 6O 6)] · H 2O is reported. The structure is compared to similar transition-metal nitrilotriacetate complexes containing different alkali cations and transition metals (Cu 2+ and Zn 2+). Inner-sphere coordination of the metals is similar, but the arrangement of counter-ions and water molecules in the unit cells vary with the size of the alkali cation.

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