Abstract
Dithienosiloles (DTSs) bearing conjugated aryl substituents on the thiophene rings (1 and 2) were prepared and their optical, electrochemical, and electron-transporting properties were investigated in comparison with those of simple DTSs having no conjugated substituents on the thiophene rings (4−6). UV absorption bands of 1 and 2 are red shifted from those of 4−6 by 40−80 nm, reflecting the expanded π-conjugation, whereas the first oxidation peaks in the cyclic voltammograms of 1 and 2 appear at potentials a little lower or almost the same energies relative to those of 4−6, depending on the nature of the substituents. The electron-transporting properties of 1 and 2 were evaluated by the performance of electroluminescent (EL) devices having vapor-deposited DTS, Alq, and TPD layers, as the electron-transport, emitter, and hole-transport, respectively. The results indicated that introduction of aryl substituents to DTSs led to inferior performance of the devices in most cases, while the device with 1c beari...
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