Effects of compatilizers on the cellular structures, interfacial morphologies and mechanical properties of PP foam composites

Abstract

AbstractThe short glass fiber (SGF)/polypropylene (PP) and ethylene-1-octene copolymer (POE)/SGF/PP foam composites were prepared by extrusion and subsequent post-foaming process in designed dies. The compatilizers, maleic anhydride grafted PP (PP-g-MAH) and maleic anhydride grafted POE (POE-g- MAH), were employed to improve the performance of the foam composites, respectively, and their influences on the cellular structures, interfacial morphologies and mechanical properties of PP foam composites were investigated. It was found that the compatilizers resulted in modified PP foam composites characterized by uniform cell size distribution, reduced cell size and increased cell density except POE/SGF/PP with POE-g-MAH. The obvious enhanced SGF-matrix interfacial bonding was observed from the SEM examination, and POE-g-MAH also facilitated the compatibility between elastomeric particles and matrix. Testing results indicated that, by the introduction of PP-g-MAH or POE-g-MAH, the mechanical properties of PP foam composites were significantly improved, and it seemed that the PP-g-MAH was more effective in strengthening the flexural and compressive strength while POE-g-MAH greatly increased the impact toughness.