Effects of C/N ratio and dissolved oxygen on aerobic denitrification process: A mathematical modeling study

Abstract

COD to ammonium nitrogen (C/N) ratio and dissolved oxygen (DO) concentration are the most important factors affecting aerobic denitrification process, however, the effects of those on the mix-cultured aerobic denitrification process are still ambiguous. A mathematical model based on the framework of activated sludge model No. 3 (ASM3) was proposed for simulating nitrogen removal in an aerobic denitrification SBR process via anoxic/aerobic denitrification. AQUASIM 2.1G was employed for parameter estimation, sensitivity analysis and model calibration, as well as model validation. Ultimately, the impacts of the C/N ratio and the DO concentration on the aerobic denitrification process were revealed by the validated model. The model proposed well described nitrogen removal in an aerobic denitrification SBR process. The total nitrogen (TN) removal efficiency of the process increased with the increasing of C/N ratio and the decreasing of DO concentration. C/N ratio impacted the synthesis of cell internal storage products (XSTO), and the effects of DO concentration on the process resulted from the competition with substrate between heterotrophs and aerobic denitrifiers. High C/N ratio was preferred, however, the DO concentration should be maintained at a relatively lower level under the premise of ensuring the aerobic condition.