Effects of changes in land use structure on nitrogen input in the Pingzhai Reservoir watershed, a karst mountain region

Abstract

Optimizing land use composition to control nitrogen input into water bodies is one way to address surface source pollution in karst mountain regions. In this study, changes in land use, N sources, and spatial and temporal changes of N migration in the Pingzhai Reservoir watershed were evaluated from 2015 to 2021, and the relationship between land use composition and N input was elucidated. N was the main pollution in the water of the watershed; NO3− was the dominant form of N, and it did not react during migration. N came from soil, livestock manure or domestic sewage, and atmospheric deposition. Isolating the fractionation effects of source nitrogen is crucial to improve the accuracy of nitrogen and oxygen isotope traceability in the Pingzhai Reservoir. From 2015 to 2021, the grassland area in the Pingzhai Reservoir increased by 5.52%, the woodland area increased by 2.01%, the water area increased by 1.44%, the cropland decreased by 5.8%, unused land decreased by 3.18%, and construction land remained unchanged. Policies and reservoir construction were the main drivers of changes in land-use type in the catchment. Changes in land use structure affected nitrogen input patterns, with unused land having a highly significant positive correlation with inputs of NH3–N, NO2−, and TN, and construction land having a significant positive correlation with the input of NO2−. The inhibitory effect of forest and grassland on nitrogen input in the basin was offset by the promoting effect of cropland and construction land on nitrogen input, with unused land becoming a new focus area for nitrogen emissions due to a lack of environmental management. Modifying the area of different land use types in the watershed can effectively control nitrogen input to the watershed.