Effects of Ce–Co substitution on structural, magnetic and dielectric properties of M-type barium hexaferrite nanoparticles synthetized by sol–gel auto-combustion route

Abstract

M-type Ce–Co substituted barium hexaferrite nanoparticles were synthesized by sol–gel auto-combustion route. The general formula of ferrites was Ba1−xCexFe12−xCoxO19 in which the x was considered to be: x = 0, 0.1, 0.2, and 0.3. The formed phases in the samples were characterized by using X-ray diffraction, Fourier transform infrared spectroscopy, Mossbauer spectroscopy and vibrating sample magnetometer. The results indicated that an increase in substitutional ion amount caused to decrease vibration frequencies of Fe–O band in the tetrahedral site due to the substitution of heavier Co2+ ion for Fe3+ ion in the tetrahedral site. Moreover, some of Ce3+ ions was transformed to Ce4+ and consequently with change in ionic radius from 1.02 to 0.87 A. It seems to us that some of this ion substituted for Fe3+ in the octahedral 12k site. The data showed that the saturation magnetization was increased from 41.25 to 46.03 emu/g, and coercivity decreased from 5,500 to 4,700 Oe, with increasing x from 0.0 to 0.2. The network analyzer results showed that the dielectric constant and dielectric loss decreased with increasing Ce–Co substitution.