Abstract

In this work, activated carbon nanofiber(ACNF) electrodes with high double-layer capaci-tance and good rate capability were prepared from polyacrylonitrile nanofibersby optimiz-ing the carbonization temperature prior to H2O activation. The morphology of the ACNFs was observed by scanning electron microscopy. The elemental composition was determined by analysis of X-ray photoelectron spectroscopy. N2-adsorption-isotherm characteristics at 77 K were confirmedby Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. ACNFs processed at different carbonization temperatures were applied as electrodes for electrical double-layer capacitors. The experimental results showed that the surface mor-phology of the CNFs was not significantlychanged after the carbonization process, although their diameters gradually decreased with increasing carbonization temperature. It was found that the carbon content in the CNFs could easily be tailored by controlling the carbonization temperature. The specificcapacitance of the prepared ACNFs was enhanced by increasing the carbonization temperature.

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