Effects of calcination temperature of kaolinite clays on the properties of geopolymer cements

Abstract

The aim of this work is to determine the most convenient calcination temperature of kaolinite clays in view of producing geopolymer cements. In this light, the clay fractions of three kaolin minerals were used. The clay fractions were characterized (chemical and thermal analyses and X-ray diffraction) and then calcined in the temperature range of 450 and 800°C. The obtained amorphous materials were dissolved in a strongly alkaline solution in order to produce geopolymer cements whose pastes were characterized by determining their setting time, linear shrinkage and compressive strength. Hardened geopolymer cement paste samples were also submitted to X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy analyses. The setting time of geopolymer cement pastes produced from the clay fractions calcined at 450°C was very long (test samples could be handled easily only after 21days at the ambient atmosphere of the laboratory). For the clay fractions calcined between 500 and 700°C, the setting time of geopolymer cement pastes reduced with increasing temperature and varied between 130 and 40min. Above 700°C, the setting time began to increase. The linear shrinkage of the hardened geopolymer cement paste samples aged between 21 and 28days attained its lowest value around 700°C. Above 700°C, the linear shrinkage began to increase. The compressive strength of the hardened geopolymer cement paste samples was between 11.9 and 36.4MPa: it increased with samples from the clay fractions calcined between 500 and 700°C but dropped above 700°C.It can be concluded that the most convenient temperature for the calcination of kaolinite clays in view of producing geopolymer cements is around 700°C.