Abstract
(Na0.53+x K0.47)(Nb0.55Ta0.45)O3 (NKNT) ceramics prepared by a solid state process were investigated at 0 ≤ x ≤ 0.02 to determine the effects of Na content in NKNT ceramics. With Na nonstoichiometry, piezoelectric properties were varied but grains were all cube-like perovskites with no impurity phases. Piezoelectric coefficient (d 33) was sensitive to Na content while polymorphic phase transition (PPT) temperature was not. PPT temperature between orthorhombic and tetragonal phases (T O-T) was around room temperature within the compositional range tested. The highest d 33 obtained was 330 pC/N at Na0.545 (x = 0.015) increased from 310 pC/N at Na0.53 (x = 0), which was due to the morphotropic phase boundary (MPB) effect around (Na0.53K0.47) of NKNT ceramics.
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