Effects of aqueous phase recirculation in hydrothermal carbonization of sweet potato waste

Abstract

Aqueous phase recirculation was investigated in hydrothermal carbonization of sweet potato waste at 220 °C for 60 min. The result showed that the aqueous phase reuse significantly increased the hydrochar yield. The lower H/C and O/C ratios indicated that decarboxylation reaction was promoted. The CC vibration of the benzene backbone became intense, suggesting the occurrence of aromatization and polymerization reactions. Thus, the carbon content and HHV were improved. After recirculation, hydrochar showed a decrease in combustion ignition temperature whereas an increase in pyrolysis initial decomposition temperature. The burnout temperatures in combustion and terminated temperature in pyrolysis both showed an increase trend. The hydrochars obtained from the recirculation step possessed lower emissions of NOX or SO2 than that from reference step. The pyrolysis emission result showed that more high thermal stability components were formed during recirculation step. Overall, aqueous phase recirculation was a feasible way to improve hydrothermal carbonization process.