Abstract
Dealloyed Pt25Cu75 bimetallic nanoparticle electrocatalysts exhibit up to 6 times higher oxygen reduction reaction activities than Pt-C catalysts. The effects of annealing temperature and duration on the catalyst activity are studied, with annealing temperature varied from 600 {degree sign}C to 950 {degree sign}C and for 7h and 14 h. XRD and electrochemical analyses is used to obtain insight to the structural details of the catalyst samples. Information regarding extend of alloying, Pt and Cu compositions and distributions on the nanoparticles and particle (crystallite) sizes is correlated with the trends observed from mass and specific activities of the catalysts. It is found that annealing duration of 14 h offers little or no benefit to catalytic activities compared to 7 h. Pt25Cu75 annealed for 7 h, at 800 {degree sign}C was found as an optimal compromise between the extend of alloying and particle size growth to give the highest catalytic activity.
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