Effects of alumina trihydrate (ATH) and organic montmorillonite (OMMT) on asphalt fume emission and flame retardancy properties of SBS-modified asphalt

Abstract

The objective of this study was to evaluate the flame retardancy and emission properties of asphalt binders containing ATH and OMMT. Limit oxygen index test was performed to evaluate the flame retardancy of each asphalt binder. Volatile organic compound (VOC) emission properties of the asphalt mixture in the mixing process were investigated using a designed test method. Thermogravimetry and Fourier transform infrared spectroscopy were used to evaluate the thermal stability and volatile-release properties of the asphalt binders. The results indicated that both ATH and OMMT effectively suppress the VOC release of the modified asphalt. The flame retardancy and VOC-emission properties of the OMMT/ATH modified asphalt were significantly improved. The addition of ATH/OMMT delayed the thermal decomposition and exhibited good thermal-insulation performance, reducing the heat release during asphalt combustion. Additionally, The ATH/OMMT compounds prevented the breakage of molecular chains in the asphalt, promoting the charring of the asphalt during combustion. According to the engineering-property tests of modified asphalt mixtures, the ATH/OMMT significantly improved the high-temperature performance of the asphalt mixture. However, it slightly reduced the thermal-cracking resistance and moisture susceptibility of the asphalt mixture.