Effects of airflow rate distribution and nitrobenzene removal in an aquifer with a low-permeability lens during surfactant-enhanced air sparging

Abstract

The application of surfactant-enhanced air sparging (SEAS) in heterogeneous aquifers has received increasing attention. In this study, a two-dimensional laboratory visualization device was used to study the migration and distribution mechanism of airflow and the nitrobenzene removal effect in an aquifer with a low-permeability lens during AS and SEAS. Experimental results showed that the surfactant significantly reduced the blocking effect of the geological interface on airflow, and the ΔPe (the air entry pressure difference between the background media and the lens) value of the geological interface decreased from 1.1 kPa to 0.3 kPa when the surfactant concentration was 800 mg/L. When the surfactant injection location was at the center of the lens and the injection volume was 1 PV (pore volume of the lens), part of the airflow entered the lens through its below interface, which clearly improved the nitrobenzene removal inside and above the lens compared with AS remediation. However, when SEAS remediation was 24 h, the surfactant redistribution caused by air sparging resulted in the airflow entering the lens to bypass the lens again, which changed the spatial distribution of airflow rate and was not conducive to the continuous removal of nitrobenzene inside the lens.