Effects of AETiO 3 additions on phase structure, microstructure and electrical properties of (K 0.5Na 0.5)NbO 3 ceramics

Abstract

Lead-free piezoelectric ceramics with the composition of (K 0.5Na 0.5)NbO 3 (KNN) and 0.995(K 0.5Na 0.5)NbO 3–0.005AETiO 3 (AE = Mg, Ca, Sr, Ba) were successfully prepared by conventional ceramic processing. Single perovskite phase with orthorhombic syngony can be obtained in pure KNN, KNN-CT and KNN-ST ceramics. The trace amounts of secondary phase(s) can be detected in KNN-MT and KNN-BT ceramics. Ceramics of KNN-CT and KNN-ST have higher cell parameters and higher densities than those of pure KNN ceramics. Good electrical properties ( d 33 = 122 pC/N, K p = 0.38, ɛ r = 421, tan δ = 0.033 and T C = 406 °C) can be obtained in pure KNN ceramics. The KNN-CT ceramics have optimized electrical properties, which are d 33 = 116 pC/N, K p = 0.39, ɛ r = 411, tan δ = 0.024 and T C = 397 °C. Besides, the P r is 18.8 μC/cm 2 and the E c is 9.65 kV/cm for pure KNN ceramics. By adding AET to KNN, the P r values decrease with increasing the AE ions radii. The air-sintered pure KNN and KNN-CT ceramics are promising lead-free piezoelectric materials for transducer applications.