Abstract

Electronic dipole and quadrupole polarizabilities and the Sternheimer shielding or antishielding factors are calculated for several closed-shell atomic systems. The calculations are carried out by an effective-field method using the perturbed orbitals, given by the uncoupled Hartree\char22{}Fock method, as trial functions. The external field is replaced either by a mean effective field taking into account the mean coupling between the deformations of the various orbitals or by a set of effective fields, each of them being relative to a particular perturbed orbital. Numerical results obtained for the He, Ne, A, and Kr isoelectronic series show a much better agreement with the corresponding coupled values than the initial uncoupled results.

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