Abstract

An effective synthesis of optically pure macrocyclic mono- and dinuclearpolylactones is proposed, based on the condensation of a natural triol – castor oil with sebacic acid dichloride, taken in ratios 1 : 1 or 1 : 2, in boiling carbon tetrachloride in the presence of triethylamine and the catalyst N,N-dimethylaminopyridine.

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