Abstract
A composite adsorbent for the removal of radioactive cesium (137Cs) was synthesized by immobilizing potassium cobalt ferrocyanide in the micro pores of the zeolite chabazite. The synthetically optimized composite adsorbent demonstrates a rapid cesium adsorption rate under both salt-free and high-salt conditions with a high distribution coefficient of cesium (≥105 mL/g). Although both components have the same ion-exchange reaction between potassium and cesium, the reaction by ferrocyanide component was predominant, which derived hundred times higher distribution coefficient of the composite adsorbent than that of pure chabazite. A thermal stabilization process was studied for improving the storage and/or disposal stability of the spent adsorbent. The formation of a eutectic system within the spent adsorbent reduced the stabilization temperature to 1000 °C from 1200 °C. Accordingly, the leaching of cesium was remarkably reduced by the remineralization to the stable pollucite. The stable impregnation of ferrocyanide component in the chabazite pores derived the reduction of cesium volatility enabling the high temperature stabilization method. Our experimental results provide evidence that the composite adsorbent has clear advantages on the cesium removal from contaminated water and its stabilization via thermal-treatment.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
