Effective methane decomposition using spark discharge assisted laser-induced plasma: An approach based on Fourier transform infrared (FTIR) spectroscopy

Abstract

The widespread utilization of fossil fuels cause to significantly elevate greenhouse gas emissions. Consequently, the developments of the innovative methods are essential to convert methane into the green energy. Recently, significant effort is made to enhance the performance of the plasma-based conversion technologies. Here, the dissociation rate of methane into heavier hydrocarbon compounds are carefully determined by making use of a hybrid laser-induced plasma (LIP) and spark discharge (SD). Fourier-transform infrared (FTIR) spectroscopy reveals a couple of characteristic peaks after laser triggering, whose intensities notably increase at higher applied voltages. The corresponding peaks indicate the formation of heavier compounds including sp and sp2 C–H stretching bonds. The findings elucidate that the methane decomposition rate notably elevates in favor of hybrid SD-LIP against that of traditional LIP. It is worth noting that the simultaneous ablative effect of the catalyst surface to remove the carbon soot by the successive laser shots could prevent the catalytic deactivation leading to the sustained performance.