Effective disposal of methylene blue using green immobilized silver nanoparticles on graphene oxide and reduced graphene oxide sheets through one-pot synthesis.

Abstract

This study reveals the feasibility of exploring highly efficient, cost-effective, and stable green adsorbents for the treatment of contaminated water. Here silver nanoparticles (AgNPs) were immobilized onto nanosheets of graphene oxide (GO) through in situ reduction process using green tea aqueous extract. GO reduction to reduced graphene oxide (rGO) and AgNPs decoration on rGO also occurred simultaneously. The impacts of the extract concentration, contact time, and temperature on the synthesis process have been investigated. The synthesized nanocomposites were examined by XRD, FTIR, Raman, SEM, TEM, and TGA. The GO nanosheets were decorated by AgNPs with a crystalline structure and an average particle size of 25 ± 3nm. The temperature and the extract concentration were considerably affecting the type of the resulting nanocomposites. The GO/Ag nanocomposites were formed at room temperature (27°C) using different extract concentration (2-18% (v/v)), while the rGO/Ag nanocomposite was formed only at a higher temperature (95°C) with higher extract concentration (18%). The methylene blue (MB) dye was picked as a water pollutant to explore the adsorption ability of the nanocomposites. The adsorption behavior of the GO/Ag nanocomposites was examined under diverse factors (MB concentration, adsorbent dosage, pH, and contact time) to achieve optimization. The adsorption data concurs with Langmuir isotherm giving maximum adsorption up to 633mgg-1. Adsorption kinetics demonstrate good pseudo-second-order compliance. Spontaneous and endothermic nature of adsorption was affirmed via thermodynamic parameters. The nanocomposites could be utilized as eco-friendly and reliable adsorbents in wastewater treatment, as a result of their exceptional productivity and reusing potential.