Effect of ZnO filler concentration on the conductivity, structure and morphology of PVdF-HFP nanocomposite solid polymer electrolyte for lithium battery application

Abstract

The polyvinylidene difluoride-co-hexafluoropropylene (PVdF-HFP) nanocomposite solid polymer electrolyte films were developed by solution-casting method. PVdF-HFP as a polymer host, lithium perchlorate (LiClO4) as a salt for lithium ion, and ZnO nanoparticles as fillers were used to form the nanocomposite solid polymer electrolyte films. All the prepared samples were characterized by X-ray diffraction (XRD), differential scanning calorimetry, and scanning electron microscopy. The XRD patterns of the pure and nanocomposite solid polymer electrolyte samples indicate the formation of amorphous phase with 17.5 wt.% of lithium salt and ZnO fillers up to 3 wt.%. The total conductivity and lithium ion transference number were studied at room temperature by using impedance spectroscopy and Wagner’s polarization methods. The highest conductivity at room temperature for solid polymer electrolyte and nanocomposite solid polymer electrolyte are found to be 3.208 × 10−4 and 1.043 × 10−3 S/cm, respectively. Similarly, the lithium ion transference number is evaluated for the optimized solid polymer electrolyte and nanocomposite solid polymer electrolyte films with 3 wt.% of ZnO fillers. And it is found that ionic transference number could be enhanced from 92 to 95 % with the addition of nanosized ZnO fillers to the solid polymer electrolyte.