Effect of zirconia content on mechanical and thermal properties of mullite–zirconia composite

Abstract

Mullite–zirconia composites were prepared by adding various zirconia contents in the mullite ranging from 0 to 30 wt-% and sintering at 1400–1600°C for 2 h. The phase composition examined by X-ray diffraction showed that mullite was the major phase combined with developed t-ZrO2 and m-ZrO2 phase as a function of zirconia content, especially at 1600°C, wherein m-ZrO2 predominated. Density increased when the zirconia content and sintering temperature were increased ranging from 2·2 to 3·53 g cm−3. The morphology of mullite grain showed elongated grains, whereas dispersed zirconia showed equiaxed and intergranular grains. Flexural strength was continuously improved by adding zirconia during the sintering temperature ranging from 1400 to 1500°C, whereas flexural strength was initially improved up to 5 wt-% of zirconia addition and deteriorated with more than 5 wt-% of zirconia content during sintering between 1550 and 1600°C. The maximum strength, 190 MPa, was obtained when sintering mullite with 30 wt-% of zirconia content at 1500°C. The degradation of strength at high sintering temperature may be a result from more occurrence of m-ZrO2 phase. Thermal expansion of sintered specimens indicated linear change and hysteresis loop change. The hysteresis loop obtained with increased zirconia content resulted in the t–m phase transformation. Martensitic start temperature Ms was determined to be 530°C for 15 wt-% zirconia sintered at 1500°C, implying that the t–m phase transformation occurred.