Effect of Yb3+ Codoping on the Upconversion Emission in Nanocrystalline Y2O3:Er3+

Abstract

The Stokes emission of nanocrystalline and bulk Y2O3:Er3+, Yb3+ following 488 nm were reported. Two nanocrystalline samples were studied, one produced via propellant synthesis and the other via wet synthesis. Green, red, and NIR emission from the Er3+ ion was observed in both bulk and nanocrystalline samples. Emission from the 2F5/2 → 2F7/2 Yb3+ transition was also observed in the bulk and nanocrystalline samples following 488 nm excitation, thereby signifying the presence of an energy transfer process from Er3+ to Yb3+. The peaks attributed to Yb3+ emission were much less intense in the nanocrystalline material, indicating that the energy transfer process occurs less readily in this material because of the inherent high phonon energies from the adsorbed CO2 and H2O on their surface. Following excitation with 978 nm, green and red anti-Stokes luminescence was evidenced in the samples under investigation. An enhancement of the red emission is observed in both bulk and nanocrystalline samples, although to a...