Abstract

Water was found to accelerate the back reaction of CO 2 radiolysis. Concentration of carbon monoxide reached only a low level(<20 ppm in CO 2) by the radiolysis of wet carbon dioxide, while it reached much higher (>250 ppm in CO 2) by that of dry carbon dioxide. Clustered ions, O 2 ±(H 2O) m (CO 2) n , are considered for the ixidizing species responsible for the back reaction.

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