Abstract

In papermaking, mill water closure may result in a significant increase of inorganic salts in the white water. The effect of these contaminants on the performance of retention aids was evaluated, in this study, through flocculation of Precipitated Calcium Carbonate with three very high molecular weight cationic polyacrylamides of medium charge density and with different degrees of branching. Furthermore, flocs resistance and reflocculation capacity was also investigated when different types of shear forces were applied. Tests were carried out in distilled water and in industrial water containing a high concentration of cationic compounds. The flocculation, deflocculation, and reflocculation processes were monitored by evaluating particle size distribution using a light diffraction spectroscopy technique. Additionally to the effect of the cationic content of the medium, the influence of the flocculant dosage and degree of polymer branching were also studied. The effect of these parameters on the flocs stru...

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