Effect of various aqueous extracting agents on fluorescence properties of waste tea residue derived carbon dots (WTR-CDs): Comparative spectroscopic analysis.

Abstract

Fluorescent carbon dots (CDs) are one of the important carbonaceous nanomaterials in the area of nanoscience and nanotechnology because of their interesting physical as well as chemical properties. Herein we studied the effect of various aqueous extracting agents on fluorescence properties of waste tea residue-based carbon dots (WTR-CDs). WTR-CDs are firstly synthesized by utilizing kitchen waste-based carbonaceous biomass. To check the role of various aqueous media during the course of WTR-CDs synthesis from carbonized carbon powder, extraction of WTR-CDs was carried out in various kinds of aqueous media viz., only aqueous (100% water, WT), aqueous-alcoholic (10% ethanol, ET), aqueous-acidic (10% acetic acid, AA), and aqueous-basic (10% ammonia, AM). The consequences of extracting agents on the photophysical properties of final WTR-CDs-WT, WTR-CDs-ET, WTR-CDs-AA and WTR-CDs-AM were also discussed in detail. We have observed interesting blue shift fluorescence spectra in acidic medium for WTR-CDs-AA and polar protic solvents compared to polar aprotic medium. The solvatochromic behaviour of WTR-CDs-WT in model polar and non-polar solvent was also studied. The effect of cationic, anionic and non-anionic surfactants on the fluorescence of WTR-CDs-WT was also evaluated. The proposed findings may help researchers in the near future to obtain fast, easy and direct synthesize CDs from a variety of biomass-based precursors under different aqueous conditions.