Abstract
Nb carbides have attracted significant attention to enhance the resistance of tempered martensitic (TM) steel to hydrogen embrittlement (HE). However, previous studies have elucidated the role of Nb carbides in HE resistance without categorizing their types (i.e., undissolved and newly precipitated). This study focuses on the effect of “undissolved” Nb carbides on the tensile and fatigue properties of hydrogen-precharged TM steels. It validated the following two factors for the HE resistance of the TM steels containing undissolved Nb carbides: hydrogen-trapping by the carbides and refinement of prior austenite grain. The former factor rarely affected the HE resistance owing to the interfacial incoherency between the undissolved carbides and ferritic matrix. Such results are distinguished from previous studies focusing on the newly precipitated carbides. In contrast, the latter factor contributed significantly to the HE resistance via the decrease in hydrogen contents per unit surface of prior austenite grain boundaries.
Highlights
Nb carbides have attracted significant attention to enhance the resistance of tempered martensitic (TM) steel to hydrogen embrittlement (HE)
transmission electron microscopy (TEM)–energy-dispersive spectroscopy (EDS) analysis revealed the distribution of nanoscale (13 nm in average) Nb carbides in Nb2-A steel
The thermomechanical processing route employed in this work did not allow a complete dissolution of Nb carbides
Summary
Nb carbides have attracted significant attention to enhance the resistance of tempered martensitic (TM) steel to hydrogen embrittlement (HE). This study focuses on the effect of “undissolved” Nb carbides on the tensile and fatigue properties of hydrogen-precharged TM steels It validated the following two factors for the HE resistance of the TM steels containing undissolved Nb carbides: hydrogen-trapping by the carbides and refinement of prior austenite grain. The former factor rarely affected the HE resistance owing to the interfacial incoherency between the undissolved carbides and ferritic matrix Such results are distinguished from previous studies focusing on the newly precipitated carbides. The latter factor contributed significantly to the HE resistance via the decrease in hydrogen contents per unit surface of prior austenite grain boundaries. Four hydrogen-precharged TM steels were evaluated under uniaxial and cyclic loading conditions by considering the application environment of the material
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