Effect of ultrasonic impact treatment on the microstructure and properties of laser cladded CoCrFeNiMox high entropy alloy coatings

Abstract

Ultrasonic impact technology was applied to improve the property of laser cladded CoCrFeNiMox (x = 0, 0.25, 0.5, 0.75) high entropy alloy coatings on the surface of low-carbon steel. The phase structures and the microstructural characteristics were studied in detail through X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The microhardness distributions, wear resistance, and corrosion resistance of the samples are illustrated using a microhardness tester, a micro-friction and wear tester, and an electrochemical test system. Single FCC phase solid solution was identified to be the main phase structure, with the interdendritic σ phase precipitating with the increasing Mo content. Although ultrasonic impact treatment did not change the phase composition of the high-entropy alloy (HEA) cladding coatings, evident plastic deformation and broken σ phase appeared near the surface of the impacted layers. Through the combined effects of dislocation, fine-grain, and dispersion strengthening, the microhardness of the CoCrFeNiMox coatings was improved after ultrasonic impact treatment. In addition, ultrasonic impact treatment decreased the surface roughness and increased the wear resistance, and the main wear mechanism of the impacted layers changed from fatigue spalling to abrasive wear. The wear mass of the ultrasonically impacted layers was approximately 92 % of the laser cladded CoCrFeNiMox coatings. Furthermore, ultrasonic impact treatment improved the corrosion resistance of the HEA coatings.