Abstract

Storage tests were held to determine the effect of the kind and thickness of the plastic film of inpackage SO<sub>2</sub> generators on the release rate of SO<sub>2</sub> and amounts of SO<sub>2</sub> and water vapor retained within unvented containers of table grapes. An emulsion of NaHSO<sub>3</sub> with plastic polymers extruded as a thin layer on kraft paper was as effective for a firststage generator as was a two-ply tea-bag stock generator with pouches containing NaHSO<sub>3</sub> powder, and is cheaper to manufacture. As a first-stage generator, however, neither extruded strips of the emulsion on kraft paper nor perforated polyethylene film pouches containing NaHSO<sub>3</sub> powder generated SO<sub>2</sub> soon enough. Further, emulsion strips heat-sealed between polyethylene-coated paper sheets generated SO<sub>2</sub> only long enough to be satisfactory for a month as second-stage generators. The thickness of polyethylene film around the pouches of NaHSO<sub>3</sub> was more significant in rate of release of SO<sub>2</sub> than was the dose of NaHSO<sub>3</sub> up to 10 weeks of storage. Thereafter dose of the NaHSO<sub>3</sub> was marked in effect. Cellulose acetate showed considerable promise as a film regulating release of SO<sub>2</sub> for storage periods of three months. Polyethylene-coated curtains in wood lugs were more effective than kraft curtains in retaining SO<sub>2</sub> and water vapor in the unvented container.

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