Abstract

The microwave dielectric properties of Zn1.8SiO3.8 ceramics were investigated as a function of sintering conditions. A single-phase willemite structure was confirmed for Zn1.8SiO3.8 ceramics prepared by single-step or two-step sintering. In the two-step sintering, the first step was for grain growth and the second step was for densification. The densification temperature selected was 1250°C, which showed the maximum densification rate by dilatometry analysis. Using two-step sintering, the specimens sintered at 1400°C for 5min and held at 1250°C for 4–12h showed a lower quality factor (Qf) than the specimens sintered at 1350°C for 5min and held at 1250°C for 4–12h. This result could be attributed to the higher density of the latter group of specimens. For the specimen sintered at 1350°C for 5min and held at 1250°C for 4h (two-step sintering), the Qf value was higher (187,600GHz) than that of the specimen sintered at 1350°C for 4h (single-step sintering). However, all specimens showed quite similar dielectric constant (K) and temperature coefficients of resonant frequency (TCF).

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