Abstract
ABSTRACT In the current investigation, effect of triazolium-based ionic liquid 1, 4-Dimethyl- 4 H-1,2,4-triazolium iodide (DMTI) on volumetric and ultrasonic properties of binary aqueous solutions of benzamide/benzylamine is analysed at four equidistant temperatures and atmospheric pressure. Molecular interactions of DMTI in binary aqueous solutions of benzylamine/benzamide are also interpreted using density (ρ) and speed of sound (u) data along with FT-IR measurements. Different volumetric and ultrasonic parameters were also computed by employing the experimental values of density (ρ) and speed of sound (u), and are further used to elucidate various kinds of interactions in the ternary system. Volumetric and acoustic transfer parameters were further used for the computation of interaction coefficients (pair and triplet). To analyse the outcomes of the estimated parameters, spectroscopic and density-functional theory (DFT) investigations have also been carried out.
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