Abstract

20Cr-8Ni stainless steel is used to manufacture heavy castings in industrial practice. Owing to the slow solidification rate of heavy castings, the as-cast structure is usually coarse, which reduces the mechanical properties. To refine the solidification structure, the effect of titanium addition on the as-cast structure and high-temperature tensile property was investigated in the laboratory. The ingots with 0.0036, 0.2, and 0.45 mass percent titanium were produced in the laboratory. On the basis of experiment and thermodynamic calculation through Thermo-Calc software, the typical inclusions changed from dual phase Si-Mn-Ti oxides to pure TiN or complex Ti2O3 + TiN with titanium content increasing. The equiaxed grain ratio of ingot increased from 51 percent to nearly 100 percent, and the size of equiaxed grain decreased owing to heterogeneous nucleation of δ-Fe. Besides, the equilibrium solidification model changed from the FA model to the F model, and the mass fraction of ferritic phase in ingots increased from 24.8 to 42.6 percent. As a result, the yield strength and ultimate tensile strength of ingots increased gradually, but the tensile elongation changed little owing to the increase of ferritic phase mass fraction and decrease of equiaxed grain size.

Highlights

  • 20Cr-8Ni stainless steel is used to manufacture heavy castings owing to its perfect corrosion resistance and mechanical properties [1,2], such as pump casing for nuclear power

  • According to the analysis of the content, as-cast structure, microstructure, inclusions type, and properties of ingot with different titanium the following conclusions inclusions type, and tensile properties of ingot with different titanium content, the following were obtained: conclusions were obtained: (1) With the increasing titanium content, the typical inclusions changed from dual phase Si-MnTi oxides to pure TiN or complex Ti2O3 + TiN

  • The equiaxed grain ratio of ingot increased from 51 percent to nearly 100 percent, and the size of equiaxed grain decreased owing to heterogeneous nucleation of δ-Fe; (1)

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Summary

Introduction

Owing to the slow solidification rate of heavy castings, the as-cast structure is usually coarse, which reduces the mechanical properties. Oxides containing titanium are the typical inclusions formed in steel firstly [7,8,9,10,11]. Seo et al concluded that the typical inclusions changed from MnSiO3 inclusions, (Mn, Ti)-spinel oxide, to Ti2 O3 with titanium content increasing in Ti-containing steel weld metals [12]. Besides oxides rich in titanium, titanium nitride is the other typical inclusions in titanium-contained steel. Yin et al found pure TiN particles and complex TiN with Al2 O3 -MgO-TiOx cores in Ti-stabilized 17Cr austenitic stainless steel

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