Abstract
Solar cells are fabricated based on two new dyes. Dye acts as an additive to thin layer interface. The effect of the π-conjugated rigidity of the thiophene rings on the photovoltaic characteristics has been investigated. The structures of the dye 1 was based on dithieno [3,2-b:2′,3′-d] thiophene-2-cyanoacrylic acid, while dye 2 was based on [2,2':5′,2″-terthiophene]-5-cyanoacrylic acid and were confirmed by elemental analysis, mass spectrometry, 1H NMR and 13C NMR spectral data. The P3HT/dye 1/nc-TiO2 solar cell produced the highest efficiency of 0.3 % with an open circuit voltage of 0.7 V compared to dye 2 solar cell. This has been attributed to the difference in energy levels of the dyes and location of their HOMO relative to conduction and valence bands of nc-TiO2. The dye 1 has rigid fused thiophene rings and its HOMO is located between valence band of TiO2 and HOMO of P3HT which leads to improve the charge carrier separation and increase the current density to reach 1.2 mA/cm2.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
