Abstract

Dolomite is a mineral material that is formed from limestone which is mostly contains the calcite (CaCO3) and magnesite (MgCO3). This paper aimed to study on thermal decomposition of dolomite under air atmosphere. Calcination of dolomite was carried out by using furnace with heating rate of 10 °C/minute in an air atmosphere. The different temperature of calcination was varied at 400 °C, 600 °C, 800 °C, and 1000 °C within 6 hours. Phase analysis (XRD) and functional group analysis (FTIR) were carried out to analysis the dolomite after calcination. Microstructural (SEM) and Energy Dispersive X-ray (EDX) analysis showed that the main constituents of pure dolomite include CaCO3 (calcite), MgCO3 (magnesite), CaO, and MgO. From the results, XRD showed that the high intensity of CaO and MgO at 800 - 1000 °C was much stronger than that of dolomite at 400 - 600 °C. In addition, FTIR presents strong and intense bands are observed at 3632.23 and 3690.98 cm−1 (800 °C), and also 3694.03 and 3633.60 cm−1 (1000 °C) due to the calcium oxide.

Highlights

  • Dolomite, CaMg (CO3)2 is an abundant carbonate material and it coexists with calcite in nature

  • This paper aimed to study on thermal decomposition of dolomite under air atmosphere

  • Microstructural (SEM) and Energy Dispersive X-ray (EDX) analysis showed that the main constituents of pure dolomite include CaCO3, MgCO3, Calcium Oxide (CaO), and Magnesium Oxide (MgO)

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Summary

Introduction

CaMg (CO3) is an abundant carbonate material and it coexists with calcite in nature. Calcination of dolomite at higher temperature (> 450 0C) leads to covers covering of pores and the surface topography of the sample has no significant changes. Calcination of MgCO3 occur at lower temperature and much faster than CaCO3. During this process, the porosity of the dolomite structure largely increases [1,2]. Calcination of CaCO3 takes place once MgCO3 fully calcined and the particle achieves its maximum porosity and specific surface area

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