Abstract

AbstractPolyurethanes slightly crosslinked with allophanate and CC linkages have been prepared by reaction of 4,4′‐diphenylmethane diisocyanate with poly(ethylene adipate) and poly(ethylene maleate) as well as with terephthalic‐adipic copolyesterdiol and some low molecular diols.Data obtained from isothermal and dynamic thermogravimetric analysis carried out in an inert atmosphere indicate that the thermal stability of polyurethanes is independent on the crosslinking density and the structural characteristics of crosslinks and hard segments.

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