Abstract
The efficiency of luminescence quenching of the metal–organic framework {[Zn(L)(DPDC)]}n (L = 1,4,8,11-tetraazacyclotetradecane, DPDC2– = 4,4ʹ-diphenyldicarboxylate) by aromatic nitro compounds depends on their structure. Nitrobenzene and nitrotoluene derivatives are found to have a much smaller effect than phenol and aniline derivatives. It is suggested that there is no electron transfer due to π-stacking interactions in these systems and a mechanism involving resonance energy transfer due to overlap of the luminophore emission band and the absorption bands of the quenchers is more probable.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
