Abstract
The effect the difference in zero energies and entropies of isotopic forms of reagents has on the difference in free energies of the elementary act of discharge of a hydronium ion for an initial equilibrium configuration of a reaction complex and equilibrium (ground) energy levels is considered. The analysis is performed for conditions of constancy of potential and constancy of overvoltage: only in the latter case one does not have to resort to extrathermodynamic assumptions. It is shown that differences in entropies of isotopic forms play a substantial role
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
