Effect of the Active Metal on the NOx Formation during Catalytic Combustion of Ammonia SOFC Off-Gas

Abstract

Catalytic combustion of hydrogen and ammonia containing off-gas surrogate from an ammonia solid oxide fuel cell (SOFC) was studied with a focus on nitrogen oxides (NOx) mitigation. Noble and transition metals (Pt, Pd, Ir, Ru, Rh, Cu, Fe, Ni) supported on Al2O3 were tested in the range of 100 to 800 °C. The tested catalysts were able to completely convert hydrogen and ammonia present in the off-gas. The selectivity to NOx increased with reaction temperature and stagnated at temperatures of 600 °C and higher. At low temperatures, the formation of N2O was evident, which declined with increasing temperature until no N2O was observed at temperatures exceeding 400 °C. Over nickel and iridium-based catalysts, the NOx formation was reduced drastically, especially at 300 to 400 °C. To the best knowledge of the authors, the current paper is the first study about catalytic combustion of hydrogen-ammonia mixtures as a surrogate of an ammonia-fed SOFC off-gas.