Effect of texture and physical properties of catalysts on ammonia synthesis

Abstract

The catalysts with higher efficiencies at mild reaction conditions are of great importance for development of ammonia synthesis with zero CO2 emissions. Here, we report, highly efficient mixed oxide supported Ru catalysts for ammonia synthesis. MgO-CeO2 supports with different Mg and Ce contents were fabricated and loaded with 1% Ru using impregnation technique. MgO-CeO2 supported Ru catalysts demonstrated efficient ammonia synthesis. Mixed oxide MgO-CeO2 supported catalysts even with higher MgO content were established with comparable ammonia synthesis yields to that obtained from pure CeO2 supported catalyst under same reaction conditions. The catalytic activity was highly dependent on the texture and physical properties of the catalysts. Presence of highly dispersed Ce and Ru has been suggested as a possible explanation for the higher yield of ammonia obtained from Ru/MgO-CeO2 catalysts having Ru selectively deposited on CeO2.