Abstract
1. A decrease in the telomerization temperature of propylene with methyl chloroacetate from 150 to 25° leads to a decrease in the degree of rearrangement of the.(CH(CH3)nCHClCO2CH3 radicals with a 1,3-(n=1) and 1,5-(n=2) migration of hydrogen. 2. The rearrangement of the radicals with a 1,3-migration of hydrogen during telomerization is much more sensitive to variation in the reaction temperature than in the case of the 1,5-transition of hydrogen.
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