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Abstract
Heats of reaction of glycylglycine with nitric acid and potassium hydroxide solutions are determined by two calorimetric procedures at 288.15, 298.15, 308.15 K and an ionic strength of solution of 0.25, 0.50, and 0.75 in the presence of KNO3. Standard thermodynamic characteristics (ΔrH°, ΔrG°, ΔrS°, and ΔpC°) are calculated for the acid-base reactions in aqueous peptide solutions. The effects of the concentration of background electrolyte and temperature on the heats of dissociation of glycylglycine are considered.
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