Effect of temperature on the silane coupling agents when bonding core resin to quartz fiber posts

Abstract

Objectives To evaluate the effect of different silane agents and air-drying temperatures on bond strength of translucent quartz fibre posts to composite resin. Methods The post surface was etched with 10 vol% hydrogen peroxide for 20 min. A two-liquid coupling agent containing 4-methacryolxyethyl trimellitate anhydride (4-META) and γ-trimethoxysilyil propyl methacrylate (γ-MPTS) and two pre-hydrolyzed single component silanes containing 3-methacryloxypropyltrimethoxysilane (3-MPS) and glycid-oxi-propyl-trimetil-oxi-silane (GPS), respectively, were used for treating the fiber posts. Two different post-silanization drying temperatures were applied (21 and 38 °C). A dual-cure composite resin (Core Paste XP) was selected to build-up the core around posts, obtaining cylindrical specimens that were serially cut in beams and subsequently loaded in tension (μTBS) at a cross-head speed of 1 mm/min until failure. Bond strength data were statistically analyzed by two-way ANOVA and Student–Newman–Keuls tests ( α = 0.05). Results Warm air-drying determined significantly higher bond strengths ( p < 0.001) for glycid-oxi-propyl-trimetil-oxi-silane (11.6 MPa) and 4-methacryolxyethyl trimellitate anhydride/γ-trimethoxysilyil propyl methacrylate silane (11.7 MPa). These two systems exhibited lower bond strengths (6.9 and 8.8 MPa, respectively) than 3-methacryloxypropyltrimethoxysilane (11.0 MPa) when dried at 21 °C. No statistical differences were recorded for 3-methacryloxypropyltrimethoxysilane when drying at 21 or 38 °C. Significance The composition of the silane coupling agent in terms of acidic content, solvent rate or degree of hydrolysis may influence resin/post bond strength when dried at 21 °C. Drying at 38 °C most likely facilitates the evaporation of solvents present in the silane agent, resulting in increased bond strength of the composite resin to the fiber post.