Abstract
Thermodynamic functions of complex formation of 15-crown-5 ether (15C5) with sodium cation (Na+) in the mixtures of water (W) with methanol (MeOH) at different temperature have been calculated. To obtain this function two experimental methods have been used. The equilibrium constants of complex formation have been determined by conductivity measurements and the enthalpic effect of complex formation has been measured by the calorimetric method and has been also calculated using van’t Hoff’s equation. The obtained results were compared and discussed. The complexes are enthalpy stabilized but entropy destabilized.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
