Abstract

This research aims to study the effect of temperature, collecting time, and condensers on properties of pyrolysis oil. The research was done be analyzing viscosity, density, proportion of pyrolysis products and performance of each condenser towers for the pyrolysis of high-density polyethylene (HDPE) and polyethylene terephthalate (PET) in the mobile pyrolysis plant. Results showed that the main product of HDPE resin was liquid, and the main product of PET resin was solid. Since the pyrolysis of PET results in mostly solid which blocked up the pipe, the analysis of pyrolysis oil would be from the use of HDPE as a raw material. The pyrolysis of HDPE resin in the amount of 100 kg at 400, 425, and 450°C produced the amount of oil 22.5, 27, and 40.5 L, respectively. The study found that 450°C was the temperature that gives the highest amount of pyrolysis oil in the experiment. The viscosity was in the range of 3.287–4.850 cSt. The density was in the range of 0.668–0.740 kg/L. The viscosity and density were increased according to three factors: high pyrolysis temperature, number of condensers and longer sampling time. From the distillation at temperatures below 65, 65–170, 170–250, and above 250°C, all refined products in each temperature range had the carbon number according to their boiling points. The distillation of pyrolysis oil in this experiment provided high amount of kerosene, followed by gasoline and diesel.

Highlights

  • Energy is important to life and is one of the economic drivers

  • We study the temperature of the pyrolysis process to produce oil from plastic pellets, testing the properties of oil obtained at each temperature, and increasing the purity of pyrolysis oil

  • While gas could be recycled in the process as fuel, solid blocked up the pipe resulting in the termination of process. This corresponds to the study from Williams and Slaney (2007) which stated that the pyrolysis of polyethylene, polypropylene, and polystyrene mostly yield oil products, while the pyrolysis of polyethylene terephthalate (PET) results in mostly solid products

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Summary

Introduction

Energy is important to life and is one of the economic drivers. Thailand has faced with energy problems because Thailand imports energy mainly oil from middle east which affects the way of life and the overall economy of the country. Energy sustainability is one of Thai society’s problems that urgently need solutions. The utilization of energy from waste is an option that has been promoted by the government which has both direct and indirect benefits. From the Pollution Control Department’s pollution quantity survey in 2014, the amount of solid municipal waste in Thailand is 26.17 million tons per year. There is only 19% correct disposal, resulting in accumulated waste up to 19.9 million tons per year. There is an amount of landfill waste accumulated more than 300 million tons and continuously increase every year. Considering the waste composition, there are generally about 18% of plastic waste, equivalent to 3.75 million tons

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