Effect of temperature on mixing thermodynamics of a new ionic liquid: {2-Hydroxy ethylammonium formate (2-HEAF) + short hydroxylic solvents}

Abstract

Density and ultrasonic velocity of the mixtures of the new ionic liquid 2-hydroxy ethylammonium formate (2-HEAF) and short hydroxylic solvents (water, methanol, and ethanol) have been measured at the range of temperature (288.15 to 323.15) K and atmospheric pressure. The corresponding apparent molar volume and the apparent molar isentropic compressibility values have been evaluated from the experimental data and fitted to a temperature dependent Redlich–Mayer equation. From these correlations, the limiting infinite dilution values of the apparent magnitudes have also been computed. Derived properties such as isobaric expansibility and isothermal coefficient of pressure excess molar enthalpy were computed due to their importance in the study of specific molecular interactions. The new experimental data were used to test the capability of prediction of the modified Heller temperature dependent equation (MHE) and collision factor theory (CFT). The obtained results indicate that ionic liquid interactions in water are weaker than in the studied alcoholic solutions. An intersection point in isotherms of isentropic compressibility was observed for aqueous solutions which may be an indication of the clathrate structural interactions at high solvent composition. The observed inverse dependence on temperature for aqueous or alcoholic mixtures points out the special trend of packing of this ionic liquid into hydroxylic solvents and its strong dependence on steric hindrance of aliphatic residues. As previously observed, the increase in van der Waals forces due to the presence of long alkyl chain (into ionic liquid and alcohols) leads to higher interactions on mixing.