Abstract

The linewidth ΔH pp and spin-Hamiltonian parameters under temperature and high hydrostatic pressure by X-band continuous wave electron paramagnetic resonance in the K3H(SO4)2 crystal were studied. Spin-Hamiltonian parameters, direction cosines and coordination of Mn2+ ion were determined at room temperature. The pressure at 300 MPa leads to the change of hydrogen bond potential and the transition from double well to single well potential moves about 10 K towards a higher temperature.

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