Abstract

An interpretation of the optical properties of ZnSe is suggested. The interpretation is based on the anticrossing band theory, which specifies the oxygen-induced splitting of the conduction band. It is shown that the new approach provides a means for understanding the specific features of the self-activated luminescence in ZnSe:O and (ZnSe:O):Te. The effect of small (<1%) Te additives on the luminescence of ZnSe:Te in the edge spectral region is interpreted. The model of electronic transitions is presented.

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