Effect of surface treatment on the physicomechanical and thermal properties of high‐density polyethylene/olive husk flour composites

Abstract

AbstractIn this study, a particular interest was focused on the recovery of lignocellulosic waste of olive husk flour (OHF) by its incorporation as filler in manufacturing composite materials based on high‐density polyethylene (HDPE) matrix with various filler contents (10, 20, and 30 wt %). The problem of incompatibility between the hydrophilic filler and the hydrophobic matrix was treated with two methods: the first method consists of using maleic anhydride‐grafted polyethylene (MAPE) as compatibilizer in HDPE/OHF composites. The second method, was focused on the chemical modification of OHF by vinyl‐triacetoxy‐silane (VTAS). Fourier transform infrared spectroscopy is used to analyze both grafting and silanization reactions involved. Scanning electron microscopy was used to show the morphology of the flour surface. Furthermore, the physicomechanical and thermal characteristics of the various composite samples were investigated as a function of filler contents and treatment types. The results showed that the properties of the composite materials are positively affected by the silanization treatment of OHF and also by MAPE addition. However, better mechanical and thermal properties with less moisture absorption were obtained for the composite materials compatibilized with MAPE. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012