Effect of surface modification of bamboo cellulose fibers on mechanical properties of cellulose/epoxy composites

Abstract

Bamboo cellulose fibers were treated with NaOH aqueous solution and silane coupling agent, respectively, before they were applied into epoxy composites. The effect of surface modification on mechanical properties was evaluated by tensile and impact tests under controlled conditions. Compared with the untreated cellulose filled epoxy composites, the NaOH solution treatment increased the tensile strength by 34% and elongation at break by 31%. While silane coupling agent treatment produced 71% enhancement in tensile strength and 53% increase in elongation at break. The scanning electron microscopy (SEM) was used to observe the surface feature of the cellulose fibers and the tensile fractures as well as cryo-fractures of the composites. The Fourier transform infrared (FTIR) was employed to analyze the chemical structure of the cellulose fibers before and after modifications. The results indicated different mechanisms for the two modifications of cellulose. The NaOH solution partly dissolved the lignin and amorphous cellulose, which resulting in splitting the fibers into smaller size. This led to easier permeating into the gaps of the fibers for epoxy resin (EP) oligmer and forming effective interfacial adhesion. Based on the emergence of Si–O–C and Si–O–Si on the cellulose surface, it was concluded that the enhancement of mechanical properties after coupling agent modification could be ascribed to the formation of chemical bonds between the cellulose and the epoxy coupled with the coupling agent.